Would be neat if shooting the gunpowder gamble grenade with golden gun [i]significantly[/i] increased its damage. Enough damage to make it worth using a golden gun shot.
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Doesn't golden gun already give you a free gunpowder gamble grenade on each kill with the right setup?
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Even better, what if the damage of the ignition was proportional to the damage of the igniting shot? Imagine the insane one-shot raid boss clips people could get by stacking high-energy fire, font of might, and a damage perk on a heavy weapon for the ultimate explosion!