In almost every case scenario you just kill a purple glowing Target with no benefit in doing so. Volatile explosions hardly ever happen when killing optimally. The only class that truly benefits with making someone Volatile is Titans. So why can Warlocks apply two different ways with pocket singularity or astrocythe with no benefit?
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I don't know... I've seen people dominate in pvp with volatile. It's just situational and if the enemy team doesn't group up, you're also out of luck.