Not sure if this is intended or not, but the Exotic states, "Your shield throws now become shield-piercing." The melee ability works just fine, with a slight issue I will state later, but Sentinel's shield throw bounces right off. However, when you are up close inside the bubble, it stuns the champion.
Melee ability issue: When you don't deal enough damage to a Barrier Champion's bubble with the shield throw melee ability, it auto-pops the bubble, but you don't get your melee charge back. This seems to only be an issue in Grandmaster Vanguard Alerts with the high damage reduction, as I was able to stun Ultimatum Barrier Champions without an issue.
Edit: added video link
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Hi there, Thanks for reaching out to us. We understand you're experiencing some odd behavior from the Second Chance gauntlets. We can imagine how this may have impacted your experience with them. If you continue to experience what you describe, then please consider recording a short video of the issue. If you record such a video, you can upload it to a site like Youtube and share a link to it here. We'll then investigate this further.