I have 'quick scoped' a number of times without issues. I can't see the system you are on and not heard of this problem from other players before. I can only think that, unless you have a controller issue, you will need to make a deliberate attempt to zoom then fire in close order instead of both at once. You can practice on a patrol run.
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I'm on PS4 Destiny Edition so it is a brand new controller. It only happens under these circumstances, no other issues.
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Edited by Absolute Dark: 10/25/2014 8:37:18 PMI am not familiar with the new PS controllers. It could be that in the Crucible you are playing at a more aggressive rate than in any other occasion and should experiment with different input styles. You can also look in the PS forums for insight and advice.