Venus is hotter than Mercury due to its thick CO2 atmosphere. Think global warming x10000
Mercury has little atmosphere so it is cooler than Venus, on average. The side facing the sun can be hotter, but only for a short period of time. Therefor, Venus is hotter than Mercury
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If I remember correctly, Mercury's orbit around the sun is like the Earth's moon. One side constantly faces the sun. That means that one side is permanently dark, while the other is quite the opposite.
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Global Warming is a scam